The PSoC 3 architecture has multiple device families (i.e. CY8C38 family). Each family has a unique datasheet. They are categorized under Datasheets section on cypress website.
The silicon datasheet covers key features of the device, brief operational details, pinout, electrical specifications and characterization graphs. It only focuses on the silicon features. Due to programmable nature of PSoC, new analog and digital peripheral are created continuously. These peripherals are documented in the component datasheets. Some of the very common MCU peripherals like UART or SPI aren't documented in the device datasheet as they are constructed in programmable blocks, they are documented in the component datasheet.